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Petrochemical Applications
Applications
Acetic Acid
Service
Parameter(s)
Range(s)
Background
Model
Reactor system - liquid effluent
Percent H
2
O (L)
0-20%
Acetic acid - HOAC
NA
5020 (NIR)
Drying column - side
Percent H
2
O (L)
0-20%
Acetic acid - HOAC
NA
5020 (NIR)
Drying column - bottoms
PPM H
2
O
0-1,500 ppm
Acetic acid - HOAC
NA
5020 (NIR)
Flare Gas Header
PPM methyl iodide
0-1,000 PPM
CO/CO
2
/N
2
/H
2
NA
6020 (UV)
Combined off gas
PPM methyl iodide
Percent H2
0-1,000 PPM
0-30%
CO/CO
2
/N
2
/H
2
NA
6020 (UV)
Promoter off gas
Percent H
2
0-30%
CO/CO
2
/N
2
/H
2
2020
(TCD)
Steam Condensate / Leaving plant
PPM Hydrocarbons
PPM O2
0-10 ppm
0-150 ppm
Condensate (H
2
O)
CO (90%)
6650SP
/
4020
/
3000TB
(FID) + 1100A
Acetone / Phenol / Cumene
Service
Parameter(s)
Range(s)
Background
Model
Oxidizer vent gas (No. 1 & 2)
Percent O
2
0-10%, 0-25% O
2
N
2
, Cumene, H
2
O
3020P
/
3020M
(Paramagnetic spec) (total of 4 sets required)
Recycle compressor drum gas
Percent H
2
50-100% H
2
N
2
, CH
4
2020
Acetone product to storage
Percent H
2
O (L)
0-0.5%, 0-5% H
2
O (L)
Acetone
NA
5020 (NIR)
Heavy ends fired boiler
Percent O
2
0-5% O
2
Flue Gas
9060Z
ZrO2
Acrylonitrite
Service
Parameter(s)
Range(s)
Background
Model
Product storage inhibitor
PPM / Percent H
2
O (L)
Methylhydroquinone
0-2,000 ppm, 0-1%
0-100 PPM MEHQ (L)
Acrlonitrile (pure)
Acrylonitrile (pure)
NA
6020 (UV) 5020 (NIR)
Product storage / N
2
blanket
Percent O
2
0-10% O
2
AcryloVapors + N
2
3000TB
/
3020T
(Div 2)
Ammonia / Urea Fertilizer Plants
Service
Parameter(s)
Range(s)
Background
Model
Primary and secondary reformer outlet
Percent CH
4
- 3 sets
0-0.5% up to 0-20%
H
2
/CO
2
/CO/N
2
7500ZA
(NDIR)
HTS/LTS shift converter outlet
Percent CO - 2 sets
0-0.5% up to 0-5%
H
2
/CO
2
/CO/N
2
7500ZA
(NDIR)
Absorber outlet
Percent CO
2
- 2 sets
0-0.3% and 0-1.5%
H
2
/CO
2
/CO/N
2
7500ZA
(NDIR)
Methanator and NH
3
converter outlet
Percent H
2
- 2 sets
Percent O2 - 2 sets
50-100%
0-0.5% O2
N
2
/ CH
4
N2/H2/CO2
2020
/
3020M
(TCD) (Paramagnetic)
CO
2
Feed to urea plant
Percent O
2
0-1%
CO
2
/H
2
/N
2
/Ar
3000MA
Stack Gas
Percent O
2
- 2 sets
0-5% and 0-10% O
2
N
2
/CO
2
/O
2
/H
2
Ov
9060Z
ZrO2
Treated Wastewater
Oil / Hydrocarbons
0-150 ppm
Water
6650SP
Aromatics
Service
Parameter(s)
Range(s)
Background
Model
Charge heater, Naphtha splitter reboiler heater, product fractionator charge heater, etc.
Percent O
2
0-5%
Flue gas
9060Z
(ZrO2) , 7-14 sets (extractive in-situ)
BTX or Paraxylene
Service
Parameter(s)
Range(s)
Background
Model
Product separator
Percent H
2
50-100%
CH
4
+ HC's
2020
Recycle gas
Percent H
2
50-100%
CH
4
+ HC's
2020
Life gas line / N
2
header and surge hopper
Percent HC - Percent H
2
15% HC to 1% H
2
N
2
, H
2
, HC
2020
LP stream condensate
PPM Oil
0-10 ppm
Condensate
6650SP
Butadiene
Service
Parameter(s)
Range(s)
Background
Model
Oxygen in vent vapor
O
2
0-1,000 ppm
N
2
/ Trace styrene
3020T
O
2
in Butadiene product
O
2
0-30 ppm
Butadiene
3020T
Process vent - 2 sets
O
2
0-1,000 ppm
N
2
/ Hexane
3020T
Above bed #4 of main washer
1, 3 Butadiene
0-70%
Multihydrocarbons
NA
7320 (NDIR)
Above bed #4 of rectifier
Cis-2-Butene
0-10%
Multihydrocarbons
NA
7320 (NDIR)
Butadiene extraction solvent recovery process
H
2
O (L)
0-10%
NMP solvent
N-methylpyrolidone
NA
5020 NIR
Butadiene Extraction
H
2
O (L)
0-300 / 0-3,000 ppm H
2
O
DMF Dimethyl formamide
NA
5020 (NIR)
Butyl Rubber Plant
Service
Parameter(s)
Range(s)
Background
Model
Water in MethylChloride
PPM H
2
O
0-1,000 and 0-5,000 ppm
MethylChloride
NA
5020 (NIR)
Caprolactum
Service
Parameter(s)
Range(s)
Background
Model
O
2
in Cyclohexane vapor
Percent O
2
0-10%
Cyclohexane / N
2
3000MA
(5 pts, 2 systems)
CO in Cyclohexane vapor
Percent CO
0-8%
7500ZA
(Z-purged)
Nitrogen oxide feed line
Percent NO
Percent N2O
70-100%
0-2%
NO, N
2
, N
2
O
NA
7320 (NDIR)
H
2
Purity
Percent H
2
PPM CO
70-100%
0-50 ppm
N
2
(ppm CH
4
, CO)
H2
2020
/
7500ZA
(Z-purged)
Feed gas / Off gas
Percent H
2
Percent NO
Percent N2O
40-100%
0-40%
0-20%
N
2
, N
2
O, NO
N2, N2O H2
N2, NO, H2
2020
/
7500ZA
(Z-purged)
O
2
in off gas
Percent O
2
0-6%
N
2
, CO + ppm HC
3000MA
O
2
in and from off gas reactor
Percent O
2
0-6%
N
2
, CO
2
, CO
3000MA
Chlorine Manufacturing / Mercury Cell Type
Service
Parameter(s)
Range(s)
Background
Model
Electrolysis of NaCl + H
2
O
PPM O
2
PPB Hg
0-10 / 0-100 ppm
0-100 ppb
H
2
(99%)
3020P
/
6000
6000 (UV)
Copolymers
Service
Parameter(s)
Range(s)
Background
Model
PTA dust explosion monitor
Percent O
2
0-10% O
2
N
2
3020P
O
2
in vacuum pump seal tank off gas
Percent O
2
0-5%, 0-10%
N
2
3020P
EDC / VCM
Service
Parameter(s)
Range(s)
Background
Model
Absorber vent gas
Percent O
2
0-5% O
2
CO
2
/H
2
O/CL
2
/HCL
NA
Htd Paramagnetic required
Stripper vent gas
Percent O
2
0-5% O
2
CO
2
/H
2
O/CL
2
/HCL
NA
Htd Paramagnetic required
VCM vent gas
PPM O
2
0-10 / 0-100 PPM O
2
VCM (G)
3020T
H
2
O in EDC
PPM H
2
O (L)
0-50 / 0-200 PPM H
2
O
EDC (pure)
NA
5020 (NIR) Typically 4 to 5 sets
CL
2
in EDC
PPM CL
2
(L)
0-1,000 PPM CL
2
EDC (pure)
6020
(UV)
H
2
O in TCE/PCE
Percent CO
0-20%
N
2
/CO
2
/C
2
H
4
7500ZA
7320
Oxyhydrochlorination route vent gas
Percent CO
2
Percent C2H4
0-20%
0-40%
N
2
/CO
2
/C
2
H
4
7500ZA
7320
Ethyl Benzene / Skyrene Monomer
Service
Parameter(s)
Range(s)
Background
Model
Styrene Vent Gas
PPM Oxygen
0-2,000 ppm O
2
H
2
/N
2
/CO
2
/mix
3000TB
/
3020T
Transalkylation regen gas
Percent Oxygen
Percent CO / Percent CO2
0-15% O
2
0-20% CO
0-20% CO2
O
2
/N
2
/CO/CO
2
3000PB
/
3020P
/
7500ZA
(Z-purged)
Stacked Gas (2-4 sets)
Percent O
2
0-5% O
2
Flue Gas
9060Z
ZrO2
Stripped Condensate
Hydrocarbons
0-10 ppm HC
Condensate (H
2
O)
6650SP
Cooled Condensate
Hydrocarbons
0-100 ppm HC
Condensate (H
2
O)
6650SP
EB recycle stream
PPM H
2
O (L)
0-300 ppm H
2
O
Benzene
NA
5020 (NIR)
Ethylene Oxide / Ethylene Glycol
Service
Parameter(s)
Range(s)
Background
Model
Ethylene feed / Reactor inlet and reactor outlet
Percent C
2
H
4
Percent O2
0-20%, 0-40% C
2
H
4
0-10%, 0-25% O2
CO
2
/AR/CH
4
7500ZA
/
3020M
7320
3020M (Paramagnetic)
Ethylene glycol product
Percent H
2
O (L)
0-5% H
2
O
Ethylene glycol
NA
5020
Ethylene Plant
Service
Parameter(s)
Range(s)
Background
Model
Charge/Preheater Flue Gas
Percent O
2
PPM CO
0-5 / 0-10%
0-100 ppm
N
2
/CO/CO
2
/H
2
Ov
9060Z
/
7500ZA
9060Z ZrO2 (5-10 sets), 7500Z (NDIR) (5-10 sets)
H
2
S in Hydrocarbons
PPM H
2
S
0-200 pm
Ethane
6000
(UV)
Percent O
2
in mixed and exhaust air
Percent O
2
0-5%
N
2
3000P
Ethylene Product
PPM O
2
0-1 ppm
Ethylene
3000TA-XL
H
2
Purification Unit (PSA unit)
PPM CO/CH
4
/CO
2
PPM O2
0-10 ppm
H
2
7500ZA
/
3000MA
(NDIR)
Ethane Recycle
Percent Ethylene C
2
H
4
0-5%
C
2
H
6
- Ethane
7500ZA
(NDIR)
Propane Recycle
Percent Propylene C
3
H
6
0-10%
C
3
H
8
- Propane
7500ZA
(NDIR)
Oil in boiler steam condensate
PPM Oil
0-5 / 0-10 ppm
Condensate
6650SP
Hexamethylene Diamine
Service
Parameter(s)
Range(s)
Background
Model
Tank car headspace / N
2
blanketing
PPM - Percent
0-1,000 ppm, 0-1%
N
2
/ HMD vapors
3000TB
/
3020T
/
3020P
3000TB (Div 2) or
3020T (for trace),
3020P (for percent)
Maleic Anhydride (MAN)
Service
Parameter(s)
Range(s)
Background
Model
Reactor feed duct to mixer
Butane
H2Ov
0-3%
N
2
, H
2
Ov
N2, Butane
7500ZA
(NDIR) Z-purged, 7320 (NDIR)
Reactor off-gas / switch cooler
Butane
CO / CO2
Maleic Anhydride
0-1%
0-2% / 0-2%
0-2%
HC/CO/CO
2
/N
2
7500ZA
/
6000
7500 (NDIR) Z-purged, 6000 (UV)
Incinerator Stack
O
2
/ CH
4
0-25% O
2
/ 0-15 ppm
N
2
/CO
2
/CO/H
2
Ov
7500ZA
(NDIR) Z-purged
MethylMethacrylate
Service
Parameter(s)
Range(s)
Background
Model
ACH vent blower - safety
Percent O
2
0-5% O
2
(Alarm @ 2%)
N
2
+HCN+Acetone
3000TB
/
3020T
(Div 2)
Nylon 6, 6
Service
Parameter(s)
Range(s)
Background
Model
Transfer conveying system and storage - N
2
blanketing
PPM O
2
0-10 / 0-100 ppm
N
2
3000TB
8 sets or sequenced solution
PET Polyethylene Terephthalate Resin
Service
Parameter(s)
Range(s)
Background
Model
N
2
blanketing / Amorphous
PPM O
2
0-10 ppm
N
2
blanketing gas
3000TA
Upgrade of PET chips
PPM hydrocarbons
0-10 ppm
N
2
blanketing gas
4020
Polycarbonate
Service
Parameter(s)
Range(s)
Background
Model
Product conveying system
Percent O
2
0-5% / 0-10% O
2
N2 blanket gas
InstaTrans-XD
(percent; 15-30 points)
Phosgene in N
2
atmosphere
PPM COCL
2
0-100 / 0-1,000 ppm
N
2
/ CO
7500ZA
NDIR, 3 sets
NaOH in water
Percent NaOH
0-12%
H
2
O
NA
Series 5000 NIR, 2 sets
Bisphenol-A in water
Bisphenol-A
0-25, 0-100 ppm
H
2
O / NaCl
6000
UV, 2 sets
Polyester Filament Yarn
Service
Parameter(s)
Range(s)
Background
Model
Slurry mix tank (PTA + glycol)
Percent H
2
O in MEG (L)
Percent H2O (L)
0-5%
0-2%
Monoethyleneglycl
MEG + PTA
NA
5020 (NIR)
Distillation column - bottoms
Percent H
2
O (L)
0-5%
MEG
NA
5020 (NIR)
Polyethylene (LLDPE)
Service
Parameter(s)
Range(s)
Background
Model
Ethylene feed, H
2
feed, N
2
feed, Butene/Hexane feed
(Analyzed before and after the De-Oxo purification units for each feed stream prior to being fed to reactor)
PPM O
2
0-0.2 to 0-10 ppm
C
2
H
4
, H
2
, N
2
3000MA
(4 to 6 sets)
Mastermix / Feed hopper vent
Percent O
2
0-10%
N
2
3000MA
(2 sets)
Vent of N
2
/ solvent separator
PPM O
2
0-10 ppm
N
2
/HC
3000MA
Prepolmerization Process Pts
Prepolymer to storage conveyor
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
Prepolymer to reactor conveyor
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
Primary degasser
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
Polymerization Process Pts
Filter vent in recovery loop
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
Fluidized bed gas compressors
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
Discharge of conveyor blower
PPM O
2
0-10 / 0-1,000 ppm
N
2
/HC
3000MA
MPN / HPN vent header
PPM O
2
0-0.2 ppm
N
2
/HC
3000TA-XL